component | method | Reference method | Detection limit |
alkalinity | Potentiometry method | 6.2.2 in “Water and wastewater monitoring and analysis methods”
ASTMD1067
|
1mg/L CaCO3 |
Indicator method | 6.2.1 in “Water and wastewater monitoring and analysis methods”
|
– | |
Al3+ | Atomic absorption spectrometry | ASTMD857 | 0.1mg/L |
Emission spectrometry method | SY/T6404 | – | |
Ammonium
|
Nessler’s reagent method | GB/T7479
ASTMD1426 |
0.02mg/L |
Ion selective electrode method | ASTMD1426 | 0.03mg/L | |
Titration | GB/T7478 | The nitrogen content is 0.2mg/l | |
Ion chromatography | ASTMD4327 | 0.1mg/L | |
Ba2+ | Emission spectrometry | SY/T6404 | – |
Atomic absorption spectrometry | GB/T15506
ASTMD3651 |
1.7mg/L
0.03mg/L |
|
Bicarbonate | Reference alkalinity | ||
Biological oxygen demand | Biological methods | GB/T7488 | 2mg/L |
B3+ | Curcumin Spectrophotometry | HJ/T49 | 0.02mg/L |
Titration | Refer to 6.3.6.2 | – | |
Bromide | Ion chromatography | ASTMD4327 | 0.1mg/L |
Iodimetry | – | ||
Ca2+ | Emission spectrometry method | SY/T6404 | – |
Atomic absorption spectrometry | GB/T11905
ASTMD511 |
0.02mg/L
0.003mg/L |
|
EDTA titration | GB/T7476
ASTMD511 |
2mg/L
1mg/L |
|
carbonate | Reference alkalinity | ||
CO2 | Titration | 6.3 in “Water and wastewater monitoring and analysis methods”
ASTMD513 |
–
1mg/L |
Chloride | Mohr/colorimetry | ASTMD4458 | 0.5mg/L |
Mercuric nitrate method |
6.11.2 in “Water and wastewater monitoring and analysis methods” |
0.5mg/L
2.5mg/L |
|
Ion chromatography | ASTMD4327 | 0.1mg/L | |
Chromium | Atomic absorption spectrometry | ASTMD1687
SY/T5928 |
0.02mg/L
– |
Emission spectrometry method | SY/T6404 | – | |
colorimetry | ASTMD1687 | 0.5mg/L | |
Chemical oxygen demand | Open reflux method | GB/T11914
ASTMD1252 |
30mg/L
1mg/L |
conductivity | Instrumental method | 4.10 in in “Water and wastewater monitoring and analysis methods”
ASTMD1125 |
–
0.05μS/cm |
fluoride | Iron chromatography | ASTMD4327 | 0.1mg/L |
Ion selective electrode method | GB/T7484
ASTMD1179 |
0.05mg/L
0.02mg/L |
|
(OH)– | Reference alkalinity | ||
Iodide | Iodimetry | 参照6.3.7.2的操作规程 | 0.2mg/L |
Ion chromatography | ASTMD4327 | 0.1mg/L | |
Ion selective electrode method | ASTMD3869 | 0.005mg/L | |
iron | O-phenanthroline Spectrophotometry | 5.9.2 in in “Water and wastewater monitoring and analysis methods”
ASTMD1068 |
0.03mg/L
0.01mg/L |
Atomic absorption spectrometry | GB/T11911
ASTMD1068 |
0.03mg/L
0.02mg/L |
|
Emission spectrometry | SY/T6404 | – | |
Li+ | Atomic absorption spectrometry | SY/T5982
ASTMD3561 |
–
0.002mg/L |
Emission spectrometry | SY/T6404 | – | |
Mg2+ | Atomic absorption spectrometry | ASTMD511
GB/T11905 |
0.0005mg/L
0.02mg/L |
Emission spectrometry | SY/T6404 | – | |
EDTA titration | ASTMD511 | 1mg/L | |
Mn2+ | Atomic absorption spectrometry | GB/T11911
ASTMD858 |
0.03mg/L
0.01mg/L |
Emission spectrometry | SY/T6404 | – | |
Potassium periodate spectrophotometry | GB/T11906 | 0.02mg/L | |
Nitrate | Cadmium reduction method | ASTMD3867 | 0.01mg/L |
Ion chromatography | ASTMD4327 | 0.1mg/L | |
Oil and grease | Infrared spectroscopy | GB/T16488
ASTMD3921 |
0.02mg/L
0.2mg/L |
colorimetry | – | ||
Gravimetric analysis | 7.5.1 in “Water and wastewater monitoring and analysis methods”
|
10mg/L | |
Total petroleum hydrocarbon method | ASTMD3921 | 0.2mg/L | |
Organic acid | Chromatography | ASTMD5317 | 不定
Indeterminate |
dissolved oxygen | Titration | 6.4.1 in “Water and wastewater monitoring and analysis methods”
ASTMD888 |
–
0.05mg/L |
Probe method | ASTMD888
GB/T11913 |
0.05mg/L | |
colorimetry | ASTMD888 | 0.06mg/L | |
pH | PH meter | GB/T6920
ASTMD1293 |
–
– |
phosphorus | Pretreatment and conversion of orthophosphate | 6.10.1 in “Water and wastewater monitoring and analysis methods”
|
未知
unknown |
colorimetry | GB/t11893
ASTMD515 |
0.01mg/L
0.05mg/L |
|
Ion chromatography | ASTMD4327 | 0.03mg/L | |
potassium | Atomic absorption spectrometry | GB/T11904
ASTMD3561 |
0.05mg/L
0.005mg/L |
Emission spectrometry | SY/T6404 | – | |
Electric resistivity | See conductivity measurement | ||
silicon | colorimetry | ASTMD859 | 0.02mg/L |
Gravimetric analysis | ASTMD859 | 0.2mg/L | |
sodium
|
Atomic absorption spectrometry | GB/T11904
ASTMD3561 |
0.01mg/L
0.002mg/L |
Emission spectrometry | SY/T6404 | – | |
Calculation method | 未知 | unknown | |
Density(SG) | Liquid densitometer method | ASTMD1429 | unknown |
Balance method | ASTMD1429 | unknown | |
Density bottle method | ASTMD1429 | unknown | |
Sr2+ | Atomic absorption spectrometry | SY/T5982
ASTMD3920 |
–
0.03mg/L |
Emission spectrometry | SY/T6404 | – | |
sulfate | Ion chromatography | ASTMD4327 | 0.1mg/L |
Turbidimeter method | ASTMD4130 | 1mg/L | |
Gravimetric analysis | 6.15.1 in “Water and wastewater monitoring and analysis methods”
|
10mg/L | |
硫化物
sulfide |
Iodimetry | HJ/T60 | 0.4mg/L |
Ion selective electrode method | ASTMD4658 | 0.04mg/L | |
Methylene blue method | GB/T16489 | 0.02mg/L | |
Garrett gas absorption method | GB/T16783-1997 | Depends on sample solume | |
Total dissolved solids (TDS) | Calculation method | application program | unknow |
Gravimetric analysis | 4.8.3 in “Water and wastewater monitoring and analysis methods”
|
– | |
Total organic carbon (TOC) | Combustion infrared method | GB/T13193
ASTMD2579 |
0.5mg/L
1mg/L |
Total suspended solids (TSS) | Filtration method | GB/T11901 | Depends on sample volume |
turbidity | Visual turbidimeter | ASTMD1889
GB/T13200 |
–
|
Spectrophotometric method | GB/T13200 | – | |
Note: The detection limits of the methods listed in the table are for comparison purposes only. The detection limits for the laboratory analysis of actual oilfield brine may vary greatly due to interference. |